Quantitative study on the homogeneity of networks synthesized by nitroxide-mediated radical copolymerization of styrene and divinylbenzene

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dc.audience researchers es_MX
dc.contributor.author Shaghayegh Hamzehlou, 0000-0003-4562-3562
dc.contributor.author Yuri Reyes, 0000-0003-3945-2111
dc.contributor.other Leiza, José Ramón
dc.coverage UK es_MX
dc.date.accessioned 2022-11-30T22:50:43Z
dc.date.available 2022-11-30T22:50:43Z
dc.date.issued 2016
dc.description The nitroxide-mediated radical copolymerization (NMRP) of styrene and divinylbenzene was studied using a Monte Carlo simulation. The model predictions were validated by comparing to experimental results gathered from literature. Polymer network microstructure was studied through complete molar mass distribution (including the gel part) of the polymer and by quantitative representation of the homogeneity of the network, i.e. the broadness of the distribution of the molar mass between crosslinking points (Mc). The nitroxide mediated radical polymerization led to a narrower Mc distribution compared to free radical polymerization, and the average Mc did not change significantly through the reaction. The narrower Mc distribution is an indicator of more homogenous network and clarifies many conflicting statements in the literature on homogeneity of the network obtained by controlled radical polymerization. es_MX
dc.format application/pdf es_MX
dc.identificador.materia 2 es_MX
dc.identifier.uri http://hdl.handle.net/20.500.12222/323
dc.language eng es_MX
dc.publisher Elsevier es_MX
dc.rights Attribution-NonCommercial-NoDerivatives 4.0 Internacional *
dc.rights.license info:eu-repo/semantics/openAccess es_MX
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/ es_MX
dc.source.other European Polymer Journal. Vo.85 (2016) es_MX
dc.source.other ISSN:  0014-3057 es_MX
dc.subject BIOLOGÍA Y QUÍMICA es_MX
dc.subject.keywords Controlled radical polymerization es_MX
dc.subject.keywords Crosslinking es_MX
dc.subject.keywords Network homogeneity es_MX
dc.title Quantitative study on the homogeneity of networks synthesized by nitroxide-mediated radical copolymerization of styrene and divinylbenzene es_MX
dc.type article es_MX
dc.type.uri https://doi.org/10.1016/j.eurpolymj.2016.10.015 es_MX
dc.type.version info:eu-repo/semantics/publishedVersion es_MX
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